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Understanding the Atom

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Includes: Chapter 1: Protons, Neutrons, Electrons, Strong Nuclear Force, Ions, Cations, Anions, Mass Number, Atomic Mass, Atomic Number, Isotopes, Nucleus, and Relative Size of Atom, Many Examples and Calculations Worked for the Student. Chapter 2: Quantum Theory, Orbits vs. Orbitals, Orbital Shapes, Electron Configuration Diagram. Chapter 3: Writing Full Electron Configurations and Diagrams, Aufbau Rule, Hünd's Rule, Pauli Principle, and Connection between Periodic Table and Order of Filling for Electrons, Many Examples Worked for the Student. Chapter 4: Writing Abbreviated Electron Configurations and Diagrams, Noble Core and Valence Electrons, Many Examples Worked for the Student. Chapter 5: Determining the Four Quantum Numbers (Principle, Angular Momentum, Magnetic, and Spin Quantum Number), Many Examples Worked for the Student. Narration: William R. Sponholtz, III, B.S., M.S., PH.D. The DVD version is available at https://sponholtzproductions.com

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[Music]

00:06

if everything in the known universe is

00:08

composed of atoms then we should all

00:11

have a basic understanding of the atom

00:13

and the three fundamental subatomic

00:14

particles the proton the neutron and the

00:18

electron therefore the goal of this

00:25

chapter is to define and deduce the

00:28

number of protons neutrons and electrons

00:30

that an atom possesses and understand

00:33

where these subatomic particles reside

00:35

within an atom there is a great deal of

00:43

information that can be gleaned from the

00:45

periodic table in fact many refer to the

00:48

periodic table as the world's greatest

00:50

cheat sheet for example what makes

00:53

helium different from all the other

00:54

elements found within the periodic table

00:57

examining helium closer we see that the

01:00

atomic number for helium is 2 the atomic

01:03

number indicates how many protons are

01:05

found in the nucleus of an atom

01:07

thus elemental identity comes from the

01:10

number of protons in other words for

01:12

helium to be helium and must possess

01:14

only 2 protons if helium gained a proton

01:20

the atomic number would become 3 which

01:23

means it's elemental identity would also

01:25

change from helium to lithium the two

01:29

protons of helium exists at the center

01:32

of the atom called the nucleus and each

01:34

proton has a positive charge the two

01:37

similar positive charges should repel

01:39

each other what an attractive force

01:41

called a strong nuclear force helps to

01:44

overcome this repulsion and the two

01:46

subatomic particles are actually

01:48

attracted to each other

01:52

it should be noted that this attraction

01:54

only occurs at the subatomic level

01:58

the repulsions are further reduced with

02:01

the help of neutrons the neutrons are

02:06

also found inside the nucleus which are

02:08

slightly heavier than the protons and

02:10

have no charge it may help to think of a

02:13

neutron as nuclear glue that increases

02:16

the extent of the strong nuclear force

02:18

which helps hold the protons together

02:21

the sum of the protons and neutrons is

02:24

referred to as the mass number in this

02:27

example helium has two protons and two

02:29

neutrons thus the mass number is four

02:32

which is often given in the upper

02:34

left-hand corner of the element and the

02:36

atomic number is two which appears in

02:38

the lower left-hand corner

02:42

however the atomic number is often

02:45

omitted after all atomic number can be

02:48

deduced from the periodic table if the

02:50

elemental symbol is given for example

02:53

the atomic number in the lower left-hand

02:55

corner does not have to be included for

02:57

carbon if we have access to a periodic

03:00

table from the periodic table we see

03:03

that carbon has an atomic number of six

03:05

thus there are six protons present to

03:10

deduce the number of neutrons we simply

03:12

subtract the number of protons from the

03:14

mass number thus there are six neutrons

03:17

remember the mass number is the sum of

03:19

the neutrons and the protons at this

03:23

point we can introduce isotopes isotopes

03:25

are atoms with the same number of

03:27

protons but different number of neutrons

03:31

for example the two common isotopes of

03:34

carbon are carbon-12 and carbon-13 they

03:37

both have the same number of protons six

03:39

but the number of neutrons are different

03:42

carbon-12 has six and carbon-13 has

03:45

seven neutrons which were deduced from

03:47

subtracting the number of protons from

03:49

the mass number

03:52

now let's look at two isotopes of

03:55

chlorine and deduce their numbers of

03:56

protons and neutrons here again the

03:59

atomic number in the lower left-hand

04:00

corner has been omitted because we have

04:03

access to a periodic table examining the

04:08

periodic table we see that chlorine is

04:10

atomic number 17 thus both isotopes have

04:13

17 protons the mass numbers 35 and 37

04:17

then allow us to deduce the number of

04:20

neutrons for each isotope 18 and 20 the

04:26

fractional abundance of the chlorine 35

04:28

isotope is seventy five point five three

04:31

percent and the fractional abundance of

04:33

the chlorine 37 isotope is twenty four

04:36

point four seven percent put another way

04:40

in any sample of pure chlorine seventy

04:43

five point five three percent of the

04:45

sample is the chlorine 35 isotope and

04:48

twenty four point four seven percent is

04:50

the chlorine 37 isotope now let's use

04:54

this data to introduce the atomic mass

04:56

of an element the atomic mass of an

05:00

element is the weighted average of the

05:02

masses of the naturally occurring

05:03

isotopes but what are the masses of each

05:06

isotope and how are they calculated to

05:09

answer this question we need to

05:11

introduce the atomic mass unit or a mu a

05:15

protons actual weight is a fraction of a

05:18

gram

05:18

thus it is easier if we simplify this

05:20

value to one atomic mass unit although a

05:24

neutron is slightly heavier than a

05:26

proton we will also simplify this value

05:28

to 1 amu taking the weighted average of

05:32

the two chlorine isotopes means we have

05:34

to account for the fractional abundance

05:36

of both of these isotopes

05:39

thus the chlorine-35 isotope is the

05:41

major isotope and its mass needs to be

05:44

accounted for approximately 75% of the

05:47

time while the mass of the minor isotope

05:50

3/7 needs to be accounted for

05:52

approximately 25% of the time for

05:57

simplicity we have rounded the

05:58

fractional abundances and masses for

06:00

both isotopes within our calculations as

06:03

we expected the atomic mass 35.5 amu

06:08

lies closer to the mass number of the

06:10

more abundant chlorine-35 isotope in the

06:15

previous carbon example we examine two

06:17

isotopes of carbon the carbon 12 isotope

06:19

is the major isotope and its mass needs

06:22

to be accounted for ninety eight point

06:24

eight nine percent of the time while the

06:26

mass of the minor isotope carbon-14

06:28

needs to be accounted for one point one

06:31

one percent of the time as we expected

06:35

the atomic mass for carbon twelve point

06:37

O one amu lies much closer to the mass

06:40

number of the more abundant isotope thus

06:44

the atomic mass of an element depends on

06:46

both the mass and the relative abundance

06:49

of each of the elements isotopes the

06:52

third subatomic particle the electron is

06:55

a negatively charged particle that

06:56

resides outside of the nucleus within

06:58

orbitals in the next chapter we'll

07:00

examine orbitals in much more detail but

07:03

for now we will simply focus on how to

07:05

ascertain the number of electrons that

07:07

an atom possesses and how it affects the

07:10

charge of the atom the actual charge

07:13

that the positively charged proton and

07:15

negatively charged electron possesses is

07:17

very small

07:18

thus for simplicity we will assign a

07:21

positive 1 and a negative 1 charge to

07:23

these subatomic particles if there are

07:26

the same number of electrons as protons

07:27

all charges will cancel and the atom

07:30

will have no charge however if a

07:33

different number of electrons than

07:34

protons exists within an atom then the

07:37

atom will have a charge called anion and

07:39

this charge is written in the upper

07:41

right-hand corner if an atom has more

07:44

electrons than protons this ion is

07:46

called an anion which has a negative

07:48

charge and if an atom has less electrons

07:51

than protons

07:52

this ion is called a cation which has a

07:55

positive charge

07:57

for example if carbon gained an extra

08:00

electron there would be one more

08:02

electron than protons thus it would have

08:05

seven electrons and a negative one

08:07

charge

08:10

in the next couple of examples it may

08:12

help to think of an anion as an atom

08:15

that has gained electrons and a cation

08:17

as an atom that has lost electrons from

08:20

the information given we do not need to

08:22

consult a periodic table to deduce the

08:25

number of protons for the fluorine 19

08:27

anion however if the atomic number of

08:30

nine was not given we could have simply

08:32

found fluorine on the periodic table and

08:34

deduced its atomic number thus there are

08:37

nine protons the number of neutrons is

08:40

calculated from subtracting the number

08:42

of protons from the mass number which

08:45

gives 10 neutrons the negative one

08:47

charge indicates there is one extra

08:49

electron when compared to the number of

08:51

protons thus there are 10 electrons

08:55

here the atomic number of 12 is given

08:58

for the magnesium 24 cation thus there

09:01

are 12 protons again the number of

09:04

neutrons is calculated from subtracting

09:06

the number of protons from the mass

09:08

number which affords 12 neutrons and

09:10

finally the positive 2 charge indicates

09:13

we have lost 2 electrons when compared

09:16

to the number of positive charges thus

09:18

there are 10 electrons this is always a

09:21

good idea to check your work

09:23

for example if you deduced there was 12

09:25

protons and 10 electrons you can simply

09:28

add them together 12 positives with 10

09:31

negatives adds 2 plus 2 which matches

09:34

the charge of this cation it is

09:36

important to be able to quickly deduce

09:38

the quantity of each of these subatomic

09:40

particles so that you can gain a better

09:42

understanding of the atom you are

09:44

examining in fact different atoms have

09:47

distinct chemical properties and

09:48

reactivities due to the different

09:50

numbers of protons neutrons and

09:52

electrons now that we have developed

09:56

skills to deduce numbers of protons

09:59

neutrons and electrons for any isotope

10:02

or ion let us start to get a feel for

10:04

the relative sizes of these particles

10:06

within an atom we have already learned

10:09

that the proton is positively charged

10:11

and the neutron has no charge that they

10:13

both reside within the nucleus are about

10:16

the same size and they are both

10:18

approximately 2,000 times bigger than a

10:21

negatively charged electron which

10:23

resides in an orbital the term nucleus

10:26

loosely translates to little nut in

10:29

Latin

10:30

[Music]

10:37

so how small is the nucleus compared

10:40

with the size of the orbital where the

10:41

electron resides imagine you are

10:45

standing in the middle of one half of a

10:46

soccer field and you were holding a

10:49

grain of rice in your hand which

10:51

represents the size of a proton in this

10:53

analogy now imagine the size of an

10:57

electron which is one mm the size of

11:00

that grain of rice this very small

11:08

particle our electron moves rapidly and

11:11

randomly inside this giant sphere with a

11:14

fixed amount of energy this giant sphere

11:17

is called an orbital which is the whole

11:20

half of the field above and below you

11:22

this is what an atom of hydrogen is like

11:25

as you can see an atom is a whole lot of

11:28

empty space even more in mind-boggling

11:31

is the fact that an atom is so small

11:33

that a human hair is approximately 1

11:36

million carbon atoms in width

11:38

[Music]

11:50

in the early 1900's many brilliant minds

11:53

were changing the landscape of science

11:55

in particular quantum theory was

11:58

emerging and changing the way we viewed

12:00

the atom one of the great results of

12:06

quantum mechanics was the orbital which

12:08

is where the electrons reside an orbital

12:11

should never be confused with an orbit

12:13

an orbit is a mathematically defined

12:16

pathway for example how the Earth orbits

12:19

the Sun using classical Newtonian

12:22

physics we can predict where the earth

12:24

will be on the orbit at some time T and

12:27

where it was at some time T in the past

12:34

you may have seen a similar simplified

12:36

model of the atom where the electron is

12:39

orbiting the nucleus on a mathematically

12:41

defined pathway which couldn't be

12:43

further from the truth an orbital is a

12:48

much more complicated concept than an

12:50

orbit in fact we know nothing about how

12:53

the electron moves around the nucleus

12:56

thus quantum mechanics demonstrated that

12:59

electrons did not move around in neat

13:01

orbits but existed in regions called

13:04

orbitals with a fixed amount of energy

13:06

in simplest terms an orbital is a

13:09

three-dimensional region or shape and

13:12

you can expect to find an electron

13:14

inside the shape 90% of the time and may

13:17

help to think of this shape as a

13:18

boundary surface the electron is more

13:22

likely to be inside this boundary shape

13:24

rather than outside the boundary let's

13:27

apply this concept of boundary shape to

13:30

the electron of the hydrogen atom which

13:32

has one proton in the nucleus and one

13:34

electron in a surrounding orbital if you

13:37

imagine the electron is moving in a

13:39

random manner with fixed energy around

13:42

the nucleus and then imagine that we

13:44

take a picture of this electron every

13:46

second for a day a week or month

13:50

you see that all these pictures laid on

13:52

top of one another

13:53

begin to form an electron cloud around

13:55

the nucleus remember all these

13:59

hypothetical pictures or data points

14:01

represent where the electron has been

14:03

over time if we now attempt to create a

14:07

three-dimensional surface to encompass

14:10

90% of all these data points we obtain a

14:13

sphere which is often called the

14:16

boundary surface the creation of this

14:18

boundary surface for the hydrogen atom

14:20

which is called an S orbital requires

14:23

some pretty complex calculus thus if an

14:26

electron is in an orbital the electron

14:28

has a fixed amount of energy and the

14:31

orbital is a three-dimensional region

14:33

around the nucleus that indicates the

14:36

probable location of that electron 90%

14:39

of the time there are many different

14:45

orbitals for the electrons to reside the

14:48

success of solutions or orbitals from

14:51

quantum mechanics increase in relative

14:53

energy when we add the shapes to the

14:57

energy turns we get the following

14:59

electron configuration diagram which

15:01

shows all the orbitals available for

15:03

electrons to reside the orbitals fall

15:06

into one of four broad categories s P D

15:11

and F orbitals interestingly there is

15:15

one solution each time an S orbital is

15:17

obtained three solutions of the same

15:20

energy each time a P solution is

15:22

obtained five solutions are the same

15:24

energy each time a D solution is

15:26

obtained and seven solutions of the same

15:29

energy each time an F solution is

15:31

obtained in the next chapter we will

15:34

revisit this diagram in detail to aid in

15:37

writing electron configurations for now

15:40

let's just focus on what this diagram

15:42

represents the orbitals and each of

15:46

these lines abstractly represents an

15:48

orbital for example the first line on

15:51

the electron configuration diagram is

15:53

the 1s orbital and it is a sphere this

15:56

is where the first two electrons of an

15:58

atom can be found 90% of the time

16:02

in addition all of the s orbitals are

16:05

shaped like fears the three 2p orbitals

16:11

are shaped like dumbbells oriented along

16:14

the three axis the 2px 2py and 2pz for

16:21

convenience your instructor will often

16:23

shrink them down to a third of their

16:25

size so that they are easier to draw if

16:27

we continue to go up and relative energy

16:30

the shapes of the orbitals become

16:32

increasingly more complicated as

16:34

demonstrated by the 3d orbital shapes

16:36

and it is unlikely that your instructor

16:39

will hold you accountable before these

16:41

shapes although this diagram may look

16:45

complicated remember that each line

16:47

abstractly represents an orbital and

16:50

that all these orbitals overlap on the

16:52

same atom here you can see that a 1s

16:56

orbital is the first orbital that the

16:58

electrons will reside in then the 2's

17:02

orbital is on top of that then the three

17:06

2p orbitals on top of them and so on and

17:10

so on until the necessary amount of

17:13

orbitals are present to house all of the

17:16

electrons that an atom may possess if

17:21

orbitals are where electrons can be

17:23

found 90% of the time in the next

17:25

chapter we will examine how many

17:27

electrons are in each orbital and the

17:30

order in which they are filled by an

17:31

atom

17:32

[Music]

17:40

the arrangement of electrons in an atom

17:43

is known as the atoms electron

17:45

configuration think of this as finding a

17:47

home for each electron electrons want to

17:50

be in the lowest energy arrangement

17:51

called the ground state electron

17:53

configuration and to accomplish this we

17:55

need to follow three basic rules the

17:58

off-ball principle tells us the order

18:00

the orbitals are filled

18:02

alfe ball is a german word meaning to

18:04

build up just like building a house we

18:06

need to start at the bottom floor when

18:08

that is completely finished we begin on

18:10

the next floor thus electrons are added

18:12

to the lowest energy orbital first and

18:14

then we work our way up in relative

18:16

energy this means that on the electron

18:19

configuration diagram electrons are

18:21

placed into the 1s orbital first then

18:24

the 2s followed by the 2p 3s 3p and so

18:30

on and so on until the necessary amount

18:33

of orbitals are filled to house all the

18:35

electrons that an atom may possess the

18:40

next rule is called the Pauli exclusion

18:42

principle which simply translates to

18:44

only 2 electrons per orbital with

18:46

opposite spin within the electron

18:49

configuration diagram we will represent

18:51

electrons as 1/2 arrows the first arrow

18:54

is up and the second arrow is down

18:56

remember that each line on this diagram

18:59

abstractly represents an orbital and

19:01

that each arrow represents an electron

19:03

in that orbital below the diagram is the

19:07

electron configuration notation which

19:09

utilizes exponents to indicate the

19:11

number of electrons within each orbital

19:15

the third and last rule is called hoons

19:18

rule which states orbitals of equal

19:20

energy are occupied by one electron

19:22

before any orbital is occupied by a

19:24

second electron now let's review these

19:28

three basic rules the first electron

19:30

goes into lowest energy orbital 1s

19:33

orbital which is the Aufbau rule the

19:35

second electron goes into that same

19:37

orbital with opposite spin the Pauli

19:39

exclusion principle states we can only

19:42

have two electrons per orbital thus the

19:44

third electron goes into the next

19:46

highest energy orbital the two

19:48

the fourth electron also goes into the

19:51

2's orbital but with opposite spin

19:53

followed by the fifth electron filling

19:55

one of the 2p orbitals hoon's rule

19:59

states that the six electron will go

20:00

into a different 2p orbital because we

20:03

should fill the orbitals one at a time

20:04

across an energy level before pairing

20:07

electrons subsequent electrons are added

20:10

following these three basic rules until

20:12

the required amount of electrons are

20:13

added to work this example problem we

20:29

first need to consult the periodic table

20:31

to ascertain how many electrons are in a

20:34

neutral atom of carbon in the first

20:37

chapter we learned how to quickly deduce

20:39

the number of electrons and we will need

20:42

this skill now the atomic number of

20:44

carbon is 6

20:45

thus a neutral atom of carbon has 6

20:48

electrons therefore this problem simply

20:51

translates to finding a home for 6

20:53

electrons following our three simple

20:56

rules we place all six electrons into

20:59

our diagram as shown start at the bottom

21:01

working our way up two electrons per

21:04

orbital with opposite spin and fill the

21:06

orbitals one at a time across an energy

21:08

level before pairing electrons

21:20

in this example we have one more

21:23

electron than the atomic number of

21:25

fluorine

21:25

thus examining the periodic table we see

21:28

that fluorines atomic number is nine

21:29

which means there are nine protons and

21:32

ten electrons if we have a negative one

21:34

charge thus the problem is really asking

21:37

us to find a home for 10 electrons again

21:40

following our three simple rules we

21:42

place all 10 electrons into our diagram

21:45

as shown in this example the calcium

21:55

atom has lost two electrons when

21:57

compared to the number of protons

21:58

thus examining the periodic table we see

22:01

the calcium città McNutt wente which

22:03

means there are 20 protons and 18

22:06

electrons if we have a positive 2 charge

22:12

thus the problem is really asking us to

22:14

find a home for 18 electrons again

22:17

following our three simple rules we

22:19

place all 18 electrons into our diagram

22:21

as shown

22:25

[Music]

22:34

first we need to consult the periodic

22:37

table to ascertain how many electrons

22:39

are in a neutral atom of gallium which

22:42

will be the same as the atomic number

22:43

for gallium gallium atomic number is 31

22:49

which means there are 31 electrons if

22:51

gallium has no charge thus the problem

22:54

is really asking us to find a home for

22:56

31 electrons again following our three

22:59

simple rules we place all 31 electrons

23:02

into our diagram as shown

23:06

[Music]

23:16

you are probably thinking that it is

23:18

going to be very challenging to memorize

23:20

and reproduce the electron configuration

23:23

diagram template shown however if you

23:25

have access to a periodic table you can

23:28

easily reproduce it for example if you

23:31

simply read the periodic table from left

23:33

to right the correct order of orbital

23:36

filling is obtained 1s 2s 2p 3s 3p 4s

23:45

then you go down a level for the 3d back

23:49

up to the 4p 5s down a level for the 4d

23:53

and so on in addition the periodic table

23:56

tells us how many electrons go into each

23:59

sublevel for example the s block is 2

24:03

elements across the Stu electrons can go

24:05

into all the s sub levels the P block is

24:09

6 elements across the 6 electrons can go

24:12

in all the P sub levels the D block is

24:16

10 elements across thus 10 electrons can

24:18

go in all the D sub levels and finally

24:21

the F block is 14 elements across which

24:24

means 14 electrons can go in all the F

24:27

sub levels you may notice that when we

24:32

compare the order of filling we obtained

24:35

from the periodic table to the electron

24:37

configuration diagram template they are

24:39

the same clearly having access to a

24:42

periodic table helps us reproduce the

24:44

electron configuration diagram template

24:47

thus you should practice drawing this

24:49

diagram on your own with the aid of a

24:51

periodic table until you have mastered

24:53

this skill

24:57

as you can tell the keys to writing

24:59

electron configurations are to quickly

25:01

ascertain the number of electrons for an

25:03

atom or ion from the periodic table and

25:06

to be able to quickly reproduce the

25:09

template for the electron configuration

25:10

diagram remember you can use the

25:14

periodic table to help you reproduce it

25:16

then simply follow the three basic rules

25:18

for electron configurations and you

25:21

should have no problems determining

25:22

electron configurations

25:26

[Music]

25:41

in the last chapter it may have seemed

25:43

difficult representing electron

25:45

configurations and drawing the full

25:47

electron configuration diagrams for

25:49

atoms that possessed many electrons for

25:51

example the 31 electrons that are found

25:54

in a neutral atom of gallium fortunately

25:57

there is a much easier way abbreviated

26:00

electron configurations allows to

26:01

combine the inert noble core electrons

26:04

with the remaining outermost electrons

26:06

therefore to be able to write the

26:09

abbreviated electron configuration we

26:11

need to first become familiar with noble

26:14

core electrons the noble core electrons

26:18

have the same electron configuration

26:19

often termed isoelectronic as a noble

26:23

element to better understand noble core

26:25

electrons let's return to the previous

26:27

gallium example recall the galleons

26:31

atomic number was 31 which meant we

26:34

found a home for the 31 electrons of a

26:36

neutral atom of gallium the noble

26:39

elements are the last family on the

26:41

periodic table to abbreviate the noble

26:44

core electrons for gallium we simply

26:47

slide back until we reach the first

26:49

noble element which is argon argon has

26:52

18 electrons thus we can abbreviate the

26:55

first 18 electrons of gallium as the

26:58

element argon these 18 electrons begin

27:03

at the 1s and end at the 3p orbital and

27:06

are represented by the noble element

27:09

argon in brackets clearly the

27:12

abbreviated diagram is much easier to

27:14

draw than the full electron

27:16

configuration diagram

27:17

[Music]

27:24

in this example we will first draw the

27:28

full electron configuration diagram for

27:30

a neutral atom of potassium then we will

27:33

focus on the abbreviated versions

27:38

potassium città Makhno 19 which means

27:42

there are 19 electrons for a neutral

27:43

atom of potassium

27:45

following the Alpha rule Pauli exclusion

27:47

principle hoons rule the following

27:50

diagram and electron configuration is

27:53

quickly obtained for the 19 electrons of

27:55

potassium to abbreviate the noble core

28:00

electrons for potassium we simply slide

28:02

back until we reach the first noble

28:04

element which is argon with 18 electrons

28:07

thus we can abbreviate the first 18

28:10

electrons of potassium as the element

28:13

argon the first 18 electrons of

28:17

potassium which begin at the 1s and

28:19

ended the 3p orbital are represented by

28:21

the noble element argon in brackets the

28:27

remaining electron in the 4s orbital is

28:30

the outermost electron commonly called

28:32

the valence electron it is often very

28:34

important to quickly ascertain the

28:36

number of valence electrons than an atom

28:38

possesses after all these are the

28:41

electrons that will be involved in bond

28:43

making and bond breaking the noble core

28:47

electrons will not be involved in bond

28:49

making and are often called the inert

28:51

noble core electrons thus let's focus

28:54

our efforts on the reactive valence

28:57

electrons

28:59

to answer how many valence electrons

29:02

carbon has we will first write the

29:04

abbreviated electron configuration we

29:07

see that a neutral atom of carbon has

29:09

six electrons thus the electron

29:11

configuration for the six electrons of

29:14

carbon is 1s2 2s2 2p2 however we need to

29:20

write the abbreviated electron

29:22

configuration to answer this question

29:24

thus we slide back to the nearest noble

29:26

which is helium helium will represent

29:29

the two noble core electrons which

29:32

leaves four valence electrons it should

29:35

be noted that we did not have to draw

29:37

the full or the abbreviated electron

29:39

configuration diagram to answer this

29:41

question we just needed access to a

29:44

periodic table for example if we first

29:48

slide back to the nearest noble which is

29:50

helium then we can simply count forward

29:53

to the element in question and that will

29:55

equal how many valence electrons that

29:57

atom possesses one two three four

30:02

valence electrons which matches our

30:04

result from drawing the electron

30:06

configurations

30:08

[Music]

30:10

let's try to answer one more of these

30:13

questions using only the periodic table

30:15

for phosphorous for example if we first

30:19

slide back to the nearest noble which is

30:21

neon then we can simply count forward to

30:24

the element in question and that will

30:26

equal how many valence electrons that

30:28

atom possesses which is five valence

30:30

electrons thus from the periodic table

30:34

we see that there are ten noble core

30:35

electrons which we could represent by

30:38

placing neon and brackets and the

30:40

remaining five valence electrons are

30:42

placed into the 3s and 3p orbitals which

30:46

matches the diagrams shown having the

30:56

ability to quickly ascertain the number

30:58

of valence electrons and atom has is

31:01

very important in bonding theory which

31:03

is thoroughly examined in the next DVD

31:05

of this series introduction to bonding

31:08

[Music]

31:16

the four quantum numbers are a direct

31:18

result from various quantum mechanical

31:20

equations these four quantum numbers

31:23

completely describe where an electron

31:25

can be located in a more simplified view

31:28

one could say that the four quantum

31:30

numbers give rise to the solutions or

31:33

orbitals that the electrons occupy or

31:37

that they give rise to the electron

31:39

configuration diagram shown which was

31:41

covered in Chapter two

31:43

while thorough treatment of this topic

31:45

is beyond the scope of this DVD your

31:47

instructor may ask you to assign the

31:50

four quantum numbers to an electron

31:51

thus it is worth our efforts to learn

31:53

about the four quantum numbers the four

31:56

quantum numbers are the principal

31:58

quantum number which will tell us the

32:00

energy level the electron is located the

32:03

angular momentum number which will

32:05

indicate the shape of the orbital the

32:07

magnetic quantum number which indicates

32:09

on which axis the orbital is on and the

32:13

spin quantum number which has only two

32:15

possible values plus 1/2 which is up or

32:19

minus 1/2 which is damn while this may

32:23

seem confusing it is actually very easy

32:25

to assign the four quantum numbers to an

32:27

electron as the following examples we'll

32:30

demonstrate

32:33

[Music]

32:37

after we draw the electron configuration

32:39

diagram for nitrogen we see that the

32:42

last electron occupies a 2p atomic

32:44

orbital thus the principal quantum

32:47

number which represents the energy level

32:49

is 2 the second quantum number the

32:53

angular momentum number represents the

32:56

shape of the orbital and from the chart

32:58

if the electron is in a p orbital l is

33:01

equal to 1 the third quantum number the

33:06

magnetic quantum number M have the

33:09

designations shown from minus L to plus

33:12

L thus this electron in the last 2p

33:16

orbital has the value of +1 and the last

33:22

quantum number which indicates the spin

33:25

of the electron is plus 1/2 because the

33:27

electron is pointing up thus the four

33:30

quantum numbers are 2 1 plus 1 and plus

33:34

1/2

33:37

[Music]

33:41

in the next example we are asked to

33:44

assign the four quantum numbers to the

33:45

last electron of a chloride anion from

33:49

the electron configuration diagram we

33:51

see that we need to fully describe the

33:53

last three P electron the electron is in

33:57

the third energy level thus and is three

34:00

it occupies a p orbital thus L is 1 M is

34:07

+1 and the electron is pointing down

34:11

therefore it is minus 1/2 thus the four

34:14

quantum numbers are 3 1 plus 1 and minus

34:18

1/2 in the next example we are asked to

34:26

assign the four quantum numbers to the

34:28

last electron of an atom of titanium

34:30

from the electron configuration diagram

34:33

we see that we need to fully describe

34:35

the second 3d electron the electron is

34:39

in the third energy level thus and is 3

34:42

it occupies a D orbital thus L is 2 M is

34:48

minus 1 and the electron is pointing up

34:52

therefore it is plus 1/2 thus the four

34:55

quantum numbers are 3 2 minus 1 and plus

34:59

1/2 if chemistry is considered to be the

35:05

central science than having a basic

35:07

understanding of the atom and the three

35:10

fundamental sub atomic particles the

35:12

proton the neutron and the electron is

35:15

essential after all

35:17

the student who has the ability to

35:19

understand the atom can take the next

35:21

crucial steps to comprehend many

35:24

different aspects of chemistry

35:25

[Music]

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