BrainChildren Chemistry
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BrainChildren Chemistry
Glossary A
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Coupling
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Concepts
Polymerization Termination
Termination
Children
1 Contact-Mediated Retinal-Opsin Coupling Enables Proton Pumping in Gloeobacter Rhodopsin
118 Contact-Mediated Retinal-Opsin Coupling Enables Proton Pumping in Gloeobacter Rhodopsin
1215. The chirality origin of retinal-carotenoid complex in gloeobacter rhodopsin: a temperature-dependent excitonic coupling
1218. Excitonic coupling effect on the circular dichroism spectrum of sodium-pumping rhodopsin KR2
13C Decoupling
14.12: Coupling Constants Identify Coupled Protons
1430. Coupling of protonation switches during rhodopsin activation
1456. Accurate measurements of 13C-13C J-couplings in the rhodopsin chromophore by double-quantum solid-state NMR spectroscopy
1495. Coupling of retinal isomerization to the activation of rhodopsin
1645. Effects of carboxyl-terminal truncation on the stability and G protein-coupling activity of bovine rhodopsin
17. Palladium catalyzed couplings
345. Excited states of biological chromophores studied using many-body perturbation theory: Effects of resonant-antiresonant coupling and dynamical screening
427. Coupling of protonation switches during rhodopsin activation
47 Accurate Measurements of 13C-13C J-Couplings in the Rhodopsin Chromophore by Double-Quantum Solid-State NMR Spectroscopy
53 Coupling of retinal isomerization to the activation of rhodopsin
65. The chirality origin of retinal-carotenoid complex in gloeobacter rhodopsin: a temperature-dependent excitonic coupling
68. Excitonic coupling effect on the circular dichroism spectrum of sodium-pumping rhodopsin KR2
7 Quantum-classical model of the rhodopsin retinal chromophore cis-trans photoisomerization with modified inter-subsystem coupling
806. Effects of Carboxy-Terminal Truncation on the Stability and G Protein-Coupling Activity of Bovine Rhodopsin
Acid-Catalyzed Diazonium Coupling of Aromatic Amines
Acid-Catalyzed Diazonium Coupling of Phenols
Advanced Topics in Photophysics-Photochemistry coupling
Aliphatic oxidative coupling
Alkene Coupling Constants
Alkyne Coupling Reactions
Alkyne Cross-Coupling Reactions
Amide Synthesis from Peptide Coupling
Angular Momentum Coupling
Angular Momentum Coupling Coefficients
Anisotropic Hyperfine Coupling
Anthracene oxidative coupling
Anti-periplanar coupling and chemical shifts
Antiperiplanar relationship in cross-coupling reactions
Application in Predicting Coupling Constants
Applications in cross-coupling and C-H activation
Aprotic solvents in cross-coupling reactions
Aromatic Coupling
Aromatic oxidative coupling
Assigning Vibrational Couplings
Asymmetric Cross-Coupling Reactions
Azo Coupling
Azo Coupling Reaction
Azo Coupling Reagents
Base-Catalyzed Diazonium Coupling of Aromatic Amines
Base-Catalyzed Diazonium Coupling of Phenols
Basic Processes in Photophysics-Photochemistry coupling
Biochemistry (1994), 33(24), 7587-93, 1645. Effects of carboxyl-terminal truncation on the stability and G protein-coupling activity of bovine rhodopsin
Broadband (BB) proton decoupling
Broadband Decoupling
Buchwald-Hartwig Coupling
Cadiot-Chodkiewicz Coupling
Cadiot–Chodkiewicz coupling
Carbodiimide Coupling
Carbon Decoupling
Carbon-Carbon Coupling
Carbonylative Coupling Reactions
Castro–Stephens coupling
Chan-Evans-Lam Coupling
Chemical Shift and Coupling Constants
Chemical Shift and Spin-Spin Coupling
Chemical Shift-based Residual Dipolar Couplings
Chemiosmotic Coupling
Column Coupling
Comparison of Heck reaction with other cross-coupling reactions
Composite Pulse Decoupling
Concurrent Coupling
Continuous Wave Decoupling
Copper-catalyzed cross-coupling reactions
Copper-catalyzed oxidative coupling
Correlation with Coupling Constants
Cost in cross-coupling reactions
Coupling Coefficients
coupling constant
Coupling constant and strong force
Coupling constant determination
Coupling Constant Videos
Coupling Constants
Coupling Constants Analysis
Coupling effect
Coupling Effects
Coupling Methods
Coupling Partners
Coupling patterns
Coupling reaction
Coupling reactions
Coupling Reactions of Amides
Coupling Reagents
Coupling Strength
Coupling Terms
Coupling Videos
Coupling with Mass Spectrometry
Coupling with Proton Transfer
Coupling with Separation Techniques
Covalent Coupling
Cross-Coupling
Cross-Coupling Efficiency
Cross-Coupling of Aryl Halides
Cross-coupling Reactions
Cross-coupling reactions in natural product synthesis
Cross-Coupling Reactions with Halides
Decarboxylative Couplings
Decoupling
Decoupling and Bypassing
Decoupling by Irradiation
Decoupling Strategies
Decoupling Techniques
Dehydrocoupling Reactions
Determination of Coupling Constants
Development of transition metal-catalyzed cross-coupling reactions
Diazo coupling
Diazo coupling reaction
Diazo coupling reaction videos
Diazo Coupling Reactions
Diazonium Coupling of Aromatic Amines
Diazonium Coupling of Phenols
Diazonium Coupling Reactions
Diazotization and Coupling
Difference Between Geminal and Vicinal Coupling
Dihedral Angle Constraints and J-coupling Analysis
Dipolar Coupling
Dipolar Coupling Constants
Dipolar Coupling in Crystals
Dipolar Coupling in Solid State NMR
Dipolar Coupling in Solids
Dipolar Recoupling
Direct Azo Coupling
Direct Coupling
Direct Coupling Techniques
Direct Dipolar Coupling
Direct J-Coupling
Discovery of Coupling Reactions
Donor-acceptor systems and electronic coupling
DRAMA (Dipolar Recoupling with a Magic Angle)
Dynamic Coupling
Dynamical Decoupling
EDC/NHS Coupling
Effect of heavy atoms on spin-orbit coupling
Eglinton Coupling
Electrocatalytic coupling reactions
Electrokinetic-Mass Spectrometry Coupling
Electromagnetic Coupling
Electron-Phonon Coupling
Electron-Phonon Coupling Constant
Electron-vibrational coupling
Electronic coupling
Electronic coupling calculations
Enantiotopic Proton Coupling
Ene-Yne Cross-Coupling
Energetic Coupling
Energy Coupling
Examples of J-coupling
Excitation-Contraction Coupling
Exciton coupling
Exciton states and vibronic coupling
Excitonic Coupling Effect on the Circular Dichroism Spectrum of Sodium-pumping Rhodopsin KR2
Explanation of Coupling Constants
Explanation of J-Coupling
Factors Affecting Coupling
Factors Affecting J-coupling
First-order Coupling
Forster dipole-dipole coupling
Free radical coupling
Fukuyama coupling
Geminal coupling
Glaser coupling
Glaser-Hay Coupling
Gravity Coupling Constant
Grignard reagents in cross-coupling reactions
GUT Coupling Constant
h-coupling
H+ pump coupling factor
Halogen Abstraction in Cross-Coupling Reactions
Heck Coupling
Heterocyclic oxidative coupling
Heterogeneous J-Coupling
Heteronuclear Coupling
Heteronuclear Dipolar Coupling
Heteronuclear Recoupling
Heterotopic Coupling
Higher-Order Coupling
Hirao coupling
Hiyama Coupling
Homogeneous J-Coupling
Homonuclear Coupling
Homotopic Coupling
How to Use for Coupling Constant Measurement
Hydroboration vs. Suzuki-Miyaura Coupling
Hyperfine coupling
Hyperfine Coupling Effects
Impact on Coupling Constants
Impact on Magnitude of Coupling Constants
Inclusion of additional physical effects (g., spin-orbit coupling)
Inclusion of free energy, reorganization energy, and electronic coupling factor
Indirect Coupling
Indirect Dipolar Coupling
Indirect J-Coupling
Inductive Coupling
Inductive Coupling for Wireless Communication
Interpretation of Coupling Constants
Interpreting Coupling Patterns
Introduction to J-J coupling
Introduction to Photophysics-Photochemistry coupling
Iron-Catalyzed Cross-Coupling Reactions
Iron-catalyzed oxidative coupling
Isotope effects on nuclear quadrupole coupling constants
Isotope effects on nuclear spin-spin coupling constants
Isotropic Hyperfine Coupling
J-coupling
J-Coupling (Spin-Spin Coupling)
J-Coupling Analysis
J-Coupling and Spin-Spin Splitting
J-coupling constants
J-coupling patterns
J-Couplings
J-J coupling
J-J coupling in atomic systems
J-J coupling in Diatomic Molecules
J-J coupling in Electron Paramagnetic Resonance (EPR)
J-J coupling in molecular systems
J-J coupling in Nuclear Magnetic Resonance (NMR)
J-J coupling in Polyatomic Molecules
J-J coupling in Quantum Mechanics
JJ Coupling
Journal of the American Chemical Society (2006), 128(12), 3878-9, 1456. Accurate measurements of 13C-13C J-couplings in the rhodopsin chromophore by double-quantum solid-state NMR spectroscopy
Kumada coupling
Kumada cross-coupling
Kumada-Corriu Coupling
L-S coupling
Lecture 1 Coupling Analysis in First-Order and Near-First-Order Systems
Lecture 1 Coupling Analysis in First-Order and Near-First-Order Systems (continued)
Lecture 14. Spin-Spin Coupling in Stereochemistry and Structure Determination
Lecture 15. Coupling Involving Other Nuclei
Lecture 16. Energy Level Diagrams, Spin-Orbit Coupling and the Pauli Principle
Liebeskind-Srogl Coupling
Liebeskind–Srogl coupling
Long-range Coupling
LS Coupling
Matrix representation of J-J coupling equations
Measurement of g-factor and Hyperfine Coupling Constants
Mechanism of Coupling
Metal-Catalyzed Coupling
Metal-Catalyzed Cross-Coupling Reactions
Metal-catalyzed oxidative coupling
Mode-coupling theory
Modification of Sonogashira coupling
Multiple Coupling Pathways
Naphthalene oxidative coupling
Negishi Coupling
Negishi Coupling Videos
Negishi cross-coupling
Nickel-Catalyzed Cross-Coupling
Nickel-catalyzed cross-coupling reactions
Nickel-catalyzed oxidative coupling
Nickel-Catalyzed Reductive Coupling Reactions
Noise Decoupling
Non-Adiabatic Coupling
Non-Adiabatic Couplings
Non-conventional Coupling
Non-First-Order Coupling
Nonadiabatic coupling and vibronic interactions
Nonadiabatic Couplings
Off-Resonance Decoupling
One-Bond Coupling
One-bond J-coupling
Optomechanical Coupling
Osmium-catalyzed oxidative coupling
Other metal-catalyzed oxidative coupling reactions
oxidative coupling
Oxidative coupling reactions
Palladium-catalyzed coupling
Palladium-Catalyzed Cross Coupling
Palladium-catalyzed Cross-Coupling
Palladium-catalyzed cross-coupling reactions
Palladium-catalyzed oxidative coupling
Pd-based Catalysts for Cross-Coupling Reactions
Peptide Coupling Reactions
Phenol oxidative coupling
Phonon-Photon Coupling
Phosphonium coupling
Photocatalytic Cross-Coupling Reactions
Photocatalytic oxidative coupling
Photochemical Cross-Coupling Reactions
Photophysics-Photochemistry coupling
Photophysics-Photochemistry coupling, Importance and applications
Photoredox Coupling Reactions
Photoredox Cross-Coupling Reactions
Photoreduction via Electron-Transfer Coupling
Piezoelectric Coupling
Pinacol Coupling
Pinacol coupling reaction
Plasmon-Phonon Coupling
Polypropylene
Polystyrene
Preparation of the Allyl Group via Cross-Coupling Reactions
Proton Coupling
Proton decoupling
Proton-Proton Coupling
Pseudoscalar Coupling
QCD Coupling Constant
QED Coupling Constant
Quadrupolar Coupling
Radical Cross-Coupling Reactions
Reductive and Oxidative Coupling Reactions
Reductive Azo Coupling
Reductive coupling
Reductive Coupling of Carbonyl Compounds
Reductive coupling reaction
Reductive Coupling Reactions
Relativistic Effects and Spin-Orbit Coupling
Residual Dipolar Coupling
Residual Dipolar Couplings (RDCs)
Resonant Inductive Coupling
Retinal proteins play significant roles in light-induced protons/ions transport across the cell membran A recent studied retinal protein, gloeobacter rhodopsin, functions as a proton pump, and binds the carotenoid salinixanthin in addn. to the retinal chromophor We have studied the interactions between the two chromophores as reflected in the CD spectrum of gR complex. GR exhibits a weak CD spectrum but following binding of sal, it exhibits a significant enhancement of the CD bands. To examine the CD origin, we have substituted the retinal chromophore of gR by synthetic retinal analogs, and have concluded that the CD bands originated from excitonic interaction between sal and the retinal chromophore as well as the sal chirality induced by binding to the protein. Temp. increase significantly affected the CD spectra, due to vanishing of excitonic coupling. A similar phenomenon of excitonic interaction lose between chromophores was recently reported for a photosynthetic pigment-protein complex (Nature
Rhodium-catalyzed oxidative coupling
Role of spin-orbit coupling in fluorescence
Running coupling constant
Ruthenium-catalyzed oxidative coupling
Scalar and Dipolar Coupling
Scalar Coupling
Scalar Coupling Constants
Second-order Coupling
Sequential Coupling
Shifts and coupling constants
Signal Coupling and Blocking
Simulating Coupling Constants
Singlet-Triplet Coupling
Sonogashira Coupling
Sonogashira Coupling Videos
Sonogashira Cross-Coupling
Sonogashira cross-coupling reactions
Sonogashira cross-coupling with terminal alkynes
Spatial Coupling
Spin and orbital angular momentum coupling
Spin Decoupling of Alcohols
Spin-Orbit Coupling
Spin-Orbit Coupling Effects
Spin-Orbit Coupling in Atoms
Spin-orbit coupling in band structure calculations
Spin-Phonon Coupling
Spin-Spin Coupling
Spin-Spin Coupling Constants
Spin-Spin Coupling Effects
Spin-Spin Decoupling
Spin-spin splitting and coupling
SR6 (Symmetry-based Recoupling)
Stille Coupling
Stille Coupling Videos
Strong Coupling
Strong Coupling Regime
Suzuki Coupling
Suzuki Coupling Videos
Suzuki-Miyaura Coupling
Suzuki-Miyaura Cross-Coupling
Suzuki-Miyaura Cross-Coupling Reaction
System-Bath Coupling
Techniques for Measuring Coupling Constants
Temporal Coupling
The Journal of chemical physics (2020), 153(4), 045101, 1218. Excitonic coupling effect on the circular dichroism spectrum of sodium-pumping rhodopsin KR2
Theory of Dipolar Coupling
Through-bond Coupling
Through-space Coupling
Transition Metal-Catalyzed Cross-Coupling
Transition metal-catalyzed cross-coupling reactions
Two-Bond Coupling
Two-bond J-coupling
Types of Coupling
Types of Coupling Constants
Types of Coupling Reactions
Types of Couplings
Types of Geminal Coupling
Ullmann Coupling
Ullmann coupling reaction
Understanding spin-orbit coupling
Vibrational Coupling
Vibrational Coupling Effects
Vibrational Dynamics and Coupling
Vibronic Coupling
Vicinal Coupling
Weak Coupling Regime
Winterfeldt Coupling
x 1H-13C Couplings
x 1H-15N Couplings
x 2-bond Coupling
x 3-bond Coupling