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Addition polymer

An addition polymer is a type of polymer formed by the addition reaction of many monomer molecules. These polymers are created without the loss of any small molecule or by-product, which distinguishes them from condensation polymers where each step of polymerization releases a small molecule like water or methanol.

Characteristics of Addition Polymers:

  1. Monomers: The monomers used in addition polymerization typically have double or triple bonds. Common monomers include ethylene, propylene, vinyl chloride, and Styrene.
  1. Mechanism: Addition polymerization usually involves three steps: initiation (where a reactive intermediate like a free radical is formed), propagation (where the reactive intermediate adds to monomers, forming a growing polymer chain), and termination (where the growth of the polymer chain stops).
  1. No By-products: Unlike condensation polymers, addition polymerization does not produce any by-products.
  1. High Molecular Weight: These polymers can reach very high molecular weights and long chain lengths.

Types of Addition Polymers:

  1. Polyethylene: Made from ethylene (CH₂=CH₂), used in plastic bags, bottles, and insulation.
  1. Polypropylene: Produced from propylene (CH₂=CH(CH₃)), used in automotive parts, textiles, and packaging.
  1. Polyvinyl Chloride (PVC): Made from vinyl chloride (CH₂=CHCl), used in pipes, cables, and clothing.
  1. Polystyrene: Derived from styrene (CH₂=CHC₆H₅), used in packaging, insulation, and disposable containers.
  1. Polytetrafluoroethylene (PTFE): Known as Teflon, made from tetrafluoroethylene (CF₂=CF₂), used in non-stick cookware and electrical insulation.

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